The 50-year-old actress, who is set to play 007’s leading lady in the 24th instalment of the action franchise, paired the skin tight dress with black stiletto heels for maximum sex appeal as she posed for pictures.
She kept her glossy brunette hair swept over one shoulder and wore a slick of pink lipstick on her pout.
Despite being the oldest Bond Girl in the franchise’s history, the star clearly looked like she can give her younger counterparts a run for their money with her youthful features.
Monica was joined by her co-star Daniel Craig who cut a dapper figure in a pin striped suit which consisted of a pocket square in his jacket and a striped tie over a blue shirt.
GETTYMonica was joined by 007 himself Daniel Craig who looked every inch suave
The pair gave fans a glimpse of their on-screen chemistry as Daniel rested his arm gently on her lower back for the sultry snaps.
Daniel, who began filming Spectre in December, is only contracted for one more movie and has already signalled his desire to bow out of the role after four films.
The film – which was officially announced in November – is set to be filmed at Pinewood Studios, London, Rome, Mexico City, Morocco and the Alps.
Reprising their roles for the next installment are Ralph Fiennes who takes the role of M after replacing Judi Dench – whose character was killed off during a shootout in Skyfall.
SPLASHDaniel Craig is only contracted for one more James Bond movie
Meanwhile Ben Whishaw and Naomie Harris return as Q and Miss Moneypenny respectively.
New cast members include Christoph Waltz, Lea Seydoux, Dave Bautista and Andrew Scott.
Bond 24: Spectre is scheduled to open in cinemas on November 6 this year.
FLYNETAt the age of 50 Monica is the oldest Bond Girl in the film’s history